Chemiluminescence

Chemiluminescence Chemiluminescence is the emission of light (luminescence), as the result of a chemical reaction. There may also be limited emission of heat. Given reactants A and B, with an excited intermediate◊, [A] + [B] → [◊] → [Products] + light For example, if...

Phosphorescence

Phosphorescence Phosphorescence is a process in which energy absorbed by a substance is released relatively slowly in the form of light. This is in some cases the mechanism used for “glow-in-the-dark” materials which are “charged” by exposure...

Fluorescence

Fluorescence Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore lower energy, than the absorbed...

Intersystem crossing

Intersystem crossing When an electron in a molecule with a singlet ground state is excited (via absorption of radiation) to a higher energy level, either an excited singlet state or an excited triplet state will form. A singlet state is a molecular electronic state...

Internal Conversion

Internal Conversion Internal conversion is a transition from a higher to a lower electronic state in a molecule or atom. It is sometimes called “radiation less de-excitation”, because no photons are emitted. It differs from intersystem crossing in that,...

Quantum Efficiency

Quantum Efficiency The “quantum efficiency” (Q.E.) is the ratio of the number of carriers collected by the solar cell to the number of photons of a given energy incident on the solar cell. The quantum efficiency may be given either as a function of...